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Mild and Tunable Benzoic Acid Catalysts for Rearrangement Reactions of Allylic Alcohols

  作者 MCCUBBIN J ADAM; VOTH SAMANTHA; KROKHIN OLEG V  
  选自 期刊  Journal of Organic Chemistry;  卷期  2011年76-20;  页码  8537-8542  
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[摘要]An efficient and simple catalytic method for the isomerization of readily prepared allylic alcohols is described. We focus particularly on cyclic examples and the synthesis of unusual enyne and dienols. The benzoic acid catalysts employed are commercially available and very inexpensive and can be tuned for reactivity and substrate sensitivity.

 
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