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Pd(II) conjugated chitosan nanofibre mats for application in Heck cross-coupling reactions

  作者 BRADSHAW MICHAEL; ZOU JIANLI; BYRNE LINDSAY; IYER K SWAMINATHAN; STEWART SCOTT G; RASTON COLIN L  
  选自 期刊  Chemical Communications;  卷期  2011年47-45;  页码  12292-12294  
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[摘要]Pd(II)-chitosan composite nanofibres of 62 +/- 9 nm diameter are efficient catalysts for Heck cross-coupling reactions. Using a model reaction of iodo-benzene and n-butyl acrylate, we demonstrate that this material can be used as a recyclable catalytic support with a very low loading of palladium (0.17 mol% Pd).

 
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