Catalytic Intermolecular Hetero-Dehydro-Diels-Alder Cycloadditions: Regio- and Diasteroselective Synthesis of 5,6-Dihydropyridin-2-ones

[摘要]：A novel catalyzed intermolecular heterodehydro-Diels-Alder reaction between push pull 1,3-dien-5-ynes and aldimines or silylaldimines is reported. The sequence is promoted both by gold(I) or silver(I) catalysts and leads to the diastereo- and regioselective formation of 5,6-dihydropyridin-2-ones.

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