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Acid-Chlorite Pretreatment and Liquefaction of Cornstalk in Hot-Compressed Water for Bio-oil Production

  作者 LIU HUAMIN; FENG BING; SUN RUNCANG  
  选自 期刊  Journal of Agricultural and Food Chemistry;  卷期  2011年59-19;  页码  10524-10531  
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[摘要]In this study, cornstalk was pretreated by an acid-chlorite delignification procedure to enhance the conversion of cornstalk to bio-oil in hot-compressed water liquefaction. The effects of the pretreatment conditions on the compositional and structural changes of the cornstalk and bio-oil yield were investigated. It was found that acid-chlorite pretreatment changed the main components and physical structures of cornstalk and effectively enhanced the bio-oil yield. Shorter residence time favored production of the total bio-oil products, whereas longer time led to cracking of the products. A high water loading was found to be favorable for high yields of total bio-oil and water-soluble oil. GC-MS analysis showed that the water-soluble oil and heavy oil were the complicated products of C(5-10) and C(8-11) organic compounds.

 
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