Pentametallic lanthanide-alkoxide square-based pyramids: high energy barrier for thermal relaxation in a holmium single molecule magnet

[摘要]：Pentametallic Ln complexes of formula [Ln(5)O(O(i)Pr)(13)] have been made, where Ln(III) = Sm, Gd, Tb, Ho and Er; slow magnetisation relaxation to 33 K is observed for the Ho complex with an energy barrier of ca. 400 K.

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