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Rhodium-Catalyzed Olefin Isomerization/Enantioselective Intramolecular Alder-Ene Reaction Cascade

  作者 OKAMOTO RYUICHI; OKAZAKI ERI; NOGUCHI KEIICHI; TANAKA KEN  
  选自 期刊  Organic Letters;  卷期  2011年13-18;  页码  4894-4897  
  关联知识点  
 

[摘要]The olefin isomerization/enantioselective intramolecular Alder-ene reaction cascade was achieved by using a cationic rhodium(I)/(R)-BINAP complex as a catalyst. A variety of substituted dihydrobenzofurans and dihydronaphthofurans were obtained from phenol- or naphthol-linked 1,7-enynes, respectively, with good yields and ee values.

 
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