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Synthesis of gamma-Benzopyranone by TfOH-Promoted Regioselective Cyclization of o-Alkynoylphenols

  作者 YOSHIDA MASAHITO; FUJINO YUTA; DOI TAKAYUKI  
  选自 期刊  Organic Letters;  卷期  2011年13-17;  页码  4526-4529  
  关联知识点  
 

[摘要]Regioselective cyclization of o-alkynoylphenols forming gamma-benzopyranones has been demonstrated. Trifluoromethanesulfonic acid (TfOH) induced 6-endo cyclization of o-alkynoylphenols without forming 5-exo cyclized benzofuranone derivatives to provide the corresponding gamma-benzopyranones in high yields.

 
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