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Regioselective Ring Opening and Isomerization Reactions of 3, 4-Epoxyesters Catalyzed by Boron Trifluoride

  作者 IZQUIERDO JAVIER; RODRIGUEZ SANTIAGO; GONZALEZ FLORENCI V  
  选自 期刊  Organic Letters;  卷期  2011年13-15;  页码  3856-3859  
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[摘要]Efficient ring opening of 3,4-epoxyesters with alcohols to produce 4-alkoxy-3-hydroxyesters and their isomerization into 4-ketoesters using boron trifluoride as the catalyst are presented. Both transformations are simple and efficient methods for the synthesis of the above named synthetically useful compounds.

 
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