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Eosin Y Catalyzed Visible Light Oxidative C-C and C-P bond Formation

  作者 HARI DURGA PRASAD; KOENIG BURKHARD  
  选自 期刊  Organic Letters;  卷期  2011年13-15;  页码  3852-3855  
  关联知识点  
 

[摘要]Eosin Y catalyzes efficiently the visible light mediated coupling of sp(3) C-H bonds adjacent to the nitrogen atom in tetrahydroisoquinoline derivatives in the absence of an external oxidant. Nitroalkanes, dialkyl malonates, malononitrile, and dialkyl phophonates were used as pronucleophiles in this metal-free, visible light oxidative coupling reaction.

 
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