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Ratiometric Fluorescent Sensor for Silver Ion and Its Resultant Complex for Iodide Anion in Aqueous Solution

  作者 WANG HUANHUAN; XUE LIN; JIANG HUA  
  选自 期刊  Organic Letters;  卷期  2011年13-15;  页码  3844-3847  
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[摘要]In aqueous solution, sensor DQAg can selectively detect Ag(+) based on inhibition of the resonance, demonstrating a large hypsochromic shift of 84 nm and remarkable changes in the ratio (F(481) (nm)/F(565) nm) of the emission intensity (R/R(0) up to 26-fold). Furthermore, the resultant Ag-DQAg also displays a ratiometric and highly selective response to iodide anion over other anions due to the liberation of DQAg from the complex by precipitating AgI.

 
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