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Conformationally Restricted Calix[8]arenes Substituted at All Methylene Bridges

  作者 KOGAN KATERINA; BIALI SILVIO E  
  选自 期刊  Journal of Organic Chemistry;  卷期  2011年76-17;  页码  7240-7244  
  关联知识点  
 

[摘要]Reaction under S(N)1 conditions of the octabromocalix[8]arene derivative 2d with alcohols proceeds in nonstereoselective fashion, but all-cis octaryl derivatives are the single major products in the reaction with arenes. The incorporation of aryl substituents at the bridges rigidifies the calix[8] arene skeleton.

 
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