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Metal-Free Chlorodeboronation of Organotrifluoroborates

  作者 MOLANDER GARY A; CAVALCANTI LIVIA N  
  选自 期刊  Journal of Organic Chemistry;  卷期  2011年76-17;  页码  7195-7203  
  关联知识点  
 

[摘要]A mild and metal-free method for the chlorodeboronation of organotrifluoroborates using trichloroisocyanuric acid (TCICA) was developed. Aryl-, heteroaryl-, alkenyl-, alkynyl-, and alkyltrifluoroborates were converted into the corresponding chlorinated products in good yields. This method proved to be tolerant of a broad range of functional groups.

 
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