Total syntheses of (S(p))-(+)- and (R(p))-(-)-spiniferin-1, a pair of unusual natural products with planar chirality

[摘要]：(S(p))-(+)-Spiniferin-1 and (R(p))-(-)-spiniferin-1, a pair of unusual marine natural products with planar chirality, were firstly synthesized via a polyfluoroalkanosulfonyl fluoride induced homoallylic carbocation rearrangement reaction. The chiral resolution and palladium-catalyzed beta-H elimination of allylic alcohol derivatives were considered as the key steps of these divergent syntheses.

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