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Photochemically-induced dioxygenase-type CO-release reactivity of group 12 metal flavonolate complexes

  作者 GRUBEL KATARZYNA; LAUGHLIN BRYNNA J; MALTAIS THORA R; SMITH RHETT C; ARIF ATTA M; BERREAU LISA M  
  选自 期刊  Chemical Communications;  卷期  2011年47-37;  页码  10431-10433  
  关联知识点  
 

[摘要]Exposure of 3-hydroxyflavonolate complexes of the group 12 metals to UV light under aerobic conditions results in oxidative carbon-carbon bond cleavage and CO release. This reactivity is novel in that it occurs under mild reaction conditions and suggests that light-induced CO-release reactivity involving metal flavonolate species may be possible in biological systems.

 
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