Oxidative coupling of porphyrins using copper(II) salts

[摘要]：A method for radical coupling of porphyrins using copper(II) salts as one-electron oxidants was developed. A Zn(II)-porphyrin bearing an aminophenyl group yielded porphyrin oligomers, and two tri-arylporphyrins were oxidized to form doubly and triply linked dimers. Bromination of doubly linked dimers gave macrocycles with twisted skeletons.

[全文传递流程]：

一般上传文献全文的时限在1个工作日内