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Selective oxidation of methanol to dimethoxymethane over bifunctional VO(x)/TS-1 catalysts

  作者 CHEN SHUANG; WANG SHENGPING; MA XINBIN; GONG JINLONG  
  选自 期刊  Chemical Communications;  卷期  2011年47-33;  页码  9345-9347  
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[摘要]This communication describes the design of bifunctional VO(x)/TS-1 catalysts with enhanced redox and acidic character via doping SO(4)(2-) and PO(4)(3-) for selective oxidation of methanol to dimethoxymethane. Redox sites enable the production of formaldehyde, while acidic sites favor the condensation of formaldehyde to DMM.

 
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