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Olefination Reactions Using Tetraarylphosphonium (TAP)-Supported Phosphorus Ylides

  作者 LEBEL HELENE; DAVI MICHAEL; ROY MARIENOELLE; ZEGHIDA WALID; CHARETTE ANDRE B  
  选自 期刊  Synthesis;  卷期  2011年-14;  页码  2275-2280  
  关联知识点  
 

[摘要]Tetraarylphosphonium (TAP)-supported phosphorus ylides were prepared and used in copper-catalyzed olefination reactions with diazo compounds to produce conjugated esters, amides, and phosphonates. The TAP-phosphine oxide can easily be separated from the alkene product, recycled, and reused.

 
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