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Allyl and Benzyl Dance under Basic Conditions

  作者 EL KAIM LAURENT; GRIMAUD LAURENCE; PURUMANDLA SRINIVAS REDDY  
  选自 期刊  SYNLETT;  卷期  2011年-13;  页码  1816-1820  
  关联知识点  
 

[摘要]Ugi-Smiles adducts formed from allyl (propargyl or benzyl) amine rearrange under basic condition with an allyl migration between two nitrogen atoms. The shift is reversible and may be controlled by the strength of the base used in the reaction.

 
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