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[摘要]：The transition-metal-mediated functionalization of CO(2) is currently an area attracting considerable interest due to the potential benefits of utilizing CO(2) as a C(1) feedstock. Here, recent advances in CO(2) activation and functionalization using monomeric Pd eta(1)-allyls are summarized. Subsequently, we discuss the chemistry of unusual Pd(I)-bridging allyl dimers, which may be masks for Pd eta(1)-allyl complexes, and are stable catalysts for CO(2) functionalization. |
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