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Graphene Nanosheet/Ni(2+)/Al(3+) Layered Double-Hydroxide Composite as a Novel Electrode for a Supercapacitor

  作者 GAO ZAN; WANG JUN; LI ZHANSHUANG; YANG WANLU; WANG BIN; HOU MENGJIE; HE YANG; LIU QI; MANN TOM; YANG PIAOPING; ZHANG MILIN; LIU LIANHE  
  选自 期刊  Chemistry of Materials;  卷期  2011年23-15;  页码  3509-3516  
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[摘要]A hybrid chemically converted graphene nanosheet/Ni(2+)/Al(3+) layered double-hydroxide (GNS/LDH) composite for supercapacitor material has been fabricated by a hydrothermal method. Scanning electron microscopy and transmission electron microscopy results reveal that Ni(2+)/Al(3+) LDH platelets homogeneously grew onto the surfaces of the GNSs as spacers to keep the neighboring sheets separate. Electrochemical properties were characterized by cyclic voltammetry, galvanostatic charge/discharge measurements, and electrochemical impedance spectroscopy. The composite exhibits a maximum specific capacitance of 781.5 F/g and excellent cycle life with an increase of the specific capacitance of 38.07% after 50 cycle tests. Even after 200 cycle tests, the increase of the capacitance is 22.56% compared with the initial capacitance.

 
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