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Synthesis of a D(3)-symmetric "trefoil" knotted cyclophane

  作者 ARIAS KARLA I; ZYSMANCOLMAN ELI; LOREN JON C; LINDEN ANTHONY; SIEGEL JAY S  
  选自 期刊  Chemical Communications;  卷期  2011年47-34;  页码  9588-9590  
  关联知识点  
 

[摘要]A D(3)-symmetric knotted cyclophane, with a subgraph of trefoil topology, was synthesized by cyclization of a D(3)-symmetric scaffold. Control of configuration at the three metal-based stereocenters arises from a bascule/pivot mechanism.

 
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