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Incorporation of chemical functionalities in the framework of mesoporous silica

  作者 LINARES NOEMI; SERRANO ELENA; RICO MARISA; MARIANA BALU ALINA; LOSADA ELIA; LUQUE RAFAEL; GARCIAMARTINEZ JAVIER  
  选自 期刊  Chemical Communications;  卷期  2011年47-32;  页码  9024-9035  
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[摘要]Mesoporous silica, which shows well-defined pore systems, tunable pore diameters (2-30 nm), narrow pore size distributions and high surface areas (>600 m(2) g(-1)), is frequently modified using different methodologies (including in situ and post-synthetic strategies) to introduce various chemical functionalities useful in applications like catalysis, separation, drug delivery, and sensing. This contribution aims to provide a critical overview of the various strategies to incorporate chemical functionalities in mesoporous silica highlighting the advantages of the in situ methods based on the bottom-up construction of mesoporous silica containing various chemical functionalities in its structure.

 
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