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Symmetry of Valence States of Heusler Compounds Explored by Linear Dichroism in Hard-X-Ray Photoelectron Spectroscopy

  作者 Ouardi, S; Fecher, GH; Kozina, X; Stryganyuk, G; Balke, B; Felser, C; Ikenaga, E; Sugiyama, T; Kawamura, N; Suzuki, M; Kobayashi, K  
  选自 期刊  PHYSICAL REVIEW LETTERS;  卷期  2011年107-3;  页码  36402-36402  
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[摘要]This study reports on the linear dichroism in angular-resolved photoemission from the valence band of the Heusler compounds NiTi(0.9)Sc(0.1)Sn and NiMnSb. High-resolution photoelectron spectroscopy was performed with an excitation energy of h nu = 7.938 keV. The linear polarization of the photons was changed using an in-vacuum diamond phase retarder. The valence band spectra exhibit the typical structure expected from first-principles calculations of the electronic structure of these compounds. Noticeable linear dichroism is found in the valence band of both materials, and this allows for a symmetry analysis of the contributing states. The differences in the spectra are found to be caused by symmetry-dependent angular asymmetry parameters, and these occur even in polycrystalline samples without preferential crystallographic orientation.

 
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