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[摘要]：Y(3-x)Lu(x)Al(3)MgSiO(12):Ce(3+) phosphors were prepared by aqueous sol-gel technique. Samples with 0.25, 0.5, 0.75 and 1 mol-% of Ce(3+) were fabricated and characterized by powder X-ray diffraction (XRD), photoluminescence (PL) spectroscopy, and temperature dependent luminescence to reveal the thermal quenching. Moreover, luminous efficacies (LE), CIE 1931 color points and quantum efficiencies (QE) were calculated and discussed. XRD patterns confirmed the presence of single phase garnet for all samples independent of Ce(3+) concentration and Y/Lu ratio. Phosphors showed broad band emission in the range 500-750 nm. The emission maximum shifts from 555 to 585 nm depending on the Ce(3+) concentration and Y/Lu ratio. Quantum efficiency of the phosphors decreased with rising Ce(3+) concentration and increased with increasing Lu content. (C) 2010 Elsevier B.V. All rights reserved. |
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