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Carbon Scaffolds for Stiff and Highly Conductive Monolithic Oxide-Carbon Nanotube Composites

  作者 Worsley, MA; Kucheyev, SO; Kuntz, JD; Olson, TY; Han, TYJ; Hamza, AV; Satcher, JH; Baumann, TF  
  选自 期刊  CHEMISTRY OF MATERIALS;  卷期  2011年23-12;  页码  3054-3061  
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[摘要]The ultra low density, high electrical conductivity, and mechanical robustness of carbon nanotube aerogels (SWNT-CA) make them ideal scaffolds around which to create novel composites. Here we report on the synthesis and characterization of oxide/carbon nanotube composites fabricated through the sol-gel deposition of oxide coatings (SiO(2), SnO(2) or TiO(2)) on SWNT-CA. The porous network of the SWNT-CA scaffold is retained after the deposition and drying process. In each case, the deposited oxide appears to form a uniform coating on the surfaces of aerogel ligaments. The composite materials exhibit high electrical conductivity (similar to 100 S/m) and enhanced mechanical properties relative to the uncoated SWNT-CA support. In addition, the oxide/SWNT-CA composites possess high surface areas (as high as 742 m(2)/g) and large mesopore volumes (as high as 2.2 cm(3)/g). This approach offers viability in engineering new oxide/CNT composites for applications such as energy storage, sensing, and catalysis.

 
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