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MgF(2) Doping of SmFeAsO Superconductors Prepared by Mechanical Alloying and Rapid Annealing

  作者 Shi, SL; Fang, AH; Xie, XM; Huang, FQ; Jiang, MH  
  选自 期刊  CHEMISTRY OF MATERIALS;  卷期  2011年23-12;  页码  3039-3044  
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[摘要]Magnesium and fluorine codoped Sm(1-x/2)Mg(x/2)-FeAsO(1-x)F(x) (x = 0 - 0.3) superconductors were prepared by the process of mechanical alloying and subsequent rapid sintering. The transition temperature (T(c)) increases with x and reaches 53.3 K at x = 0.3, accompanied by decreased lattice parameters. Electron-type conduction in the MgF(2)-doped samples was found by Hall-effect measurements. The higher T(c) value of Sm(1-x)Mg(x/2)FeAsO(1-x)F(x) was attributed to the larger disorder and a higher internal pressure from the Sm and O sites, similar to the case of (Ln(1-x)M(x))(2)CuO(4) superconductors (where Ln is a rare-earth element and M = Ca, Sr, Ba).

 
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