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A Green Procedure for the Diazotization-Iodination of Aromatic Amines under Aqueous, Strong-Acid-Free Conditions

  作者 TRUSOVA MARINA E; KRASNOKUTSKAYA ELENA A; POSTNIKOV PAVEL S; CHOI YOUNGHWA; CHI KIWHAN; FILIMONOV VICTOR D  
  选自 期刊  Synthesis;  卷期  2011年-13;  页码  2154-2158  
  关联知识点  
 

[摘要]A convenient and mild one-pot method for the synthesis of iodoarenes in high yields by the sequential diazotization-iodination of aromatic amines with a reusable polymeric diazotization agent in the presence of p-toluenesulfonic acid at room temperature in water was developed. The method is general and is the greenest alternative of the known diazotization-iodination methods. The method is also effective for the preparation of 1H-benzo[d][1,2,3]triazole and benzo[d][1,2,3]thiadiazole.

 
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