Simple N-Sulfinyl-Based Chiral Sulfur-Olefin Ligands for Rhodium-Catalyzed Asymmetric 1,4-Additions

[摘要]：A variety of N-sulfinyl-based chiral sulfur-olefin ligands has been successfully developed for the first time for rhodium-catalyzed highly efficient and enantioselective 1,4-additions. The ease of synthesis and needless consideration of the carbon chirality makes this novel type of ligands attractive for asymmetric catalysis.

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