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An Efficient Stereoselective Total Synthesis of Synargentolide A and Its Epimer

  作者 Das, B; Balasubramanyam, P; Veeranjaneyulu, B; Reddy, GC  
  选自 期刊  Helvetica Chimica Acta;  卷期  2011年94-5;  页码  881-884  
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[摘要]The stereoselective total synthesis of a naturally occurring alpha-pyrone (= 2H-pyran-2-one) derivative, synargentolideA(1), and of its epimer 2 (with the originally proposed structure of synargentolideA) was efficiently accomplished involving D-tartaric acid as the starting material and an olefin cross-metathesis reaction as the key step.

 
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