DIBAL-Mediated Reductive Transformation of trans-Dimethyl Tartrate Acetonide into epsilon-Hydroxy alpha,beta-Unsaturated Ester and Its Derivatives

[摘要]：Stepwise, selective DIBAL reduction of the acetonide diester derived from tartaric acid followed by the Horner-Emmons reaction effectively provided desymmetrized hydroxy mono-olefination products in a one-pot operation.

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