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Sodium Nitrite Catalyzed Aerobic Oxidative Deoximation under Mild Conditions

  作者 ZHANG GUOFU; WEN XIN; WANG YONG; MO WEIMIN; DING CHENGRONG  
  选自 期刊  Journal of Organic Chemistry;  卷期  2011年76-11;  页码  4665-4668  
  关联知识点  
 

[摘要]A mild, simple process for the effective deoximation of a wide range of ketoximes and aldoximes has been developed, which utilizes available NaNO2 as the catalyst and molecular oxygen as the green oxidant. Notably Amberlyst-15, which acts as the initiator of NaNO2, can be reused without regeneration. This environmentally benign protocol could provide a valuable synthetic method for practical applications.

 
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