Enantioselective alpha-Amination of Branched Aldehydes Promoted by Simple Chiral Primary Amino Acids

[摘要]：A series of simple chiral primary amino acids were first successfully applied to promote the enantioselective alpha-amination of branched aldehydes with azadicarboxylates and the desired adducts bearing quaternary stereogenic centers were obtained in excellent yields (up to 99%) and enantioselectivities (up to 97% ee).

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