Regio- and Stereoselective Synthesis of 2-Amino-1,3-diene Derivatives by Ruthenium-Catalyzed Coupling of Ynamides and Ethylene

[摘要]：A ruthenium-catalyzed hydrovinylation-type cross-coupling of ynamides and ethylene proceeds via ruthenacyclopentene to give 2-aminobuta-1,3-diene derivatives in a highly regioselective manner. It was also demonstrated that 2-aminobuta-1,3-diene derivatives reacted with various dienophiles or singlet oxygen to give a cyclic enamide derivative.

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