Hybrid Polyoxometalates: Keggin and Dawson Silyl Derivatives as Versatile Platforms

[摘要]：A new series of polyoxometalate-based hybrids has been synthesized. These covalently linked organic-inorganic materials represent valuable elementary building blocks ready for postfunctionalization, using classical organic reactions and couplings. This approach is exemplified by the grafting of an organic chromophore via a Sonogashira coupling.

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