【文章名】Triethylamine-Catalyzed Efficient Synthesis of Oxathiolanes Containing a Highly Polarized Carbon-Carbon Double Bond from Reaction of Malononitrile, Carbon Disulfide (CS2), and Oxiranes
Triethylamine-Catalyzed Efficient Synthesis of Oxathiolanes Containing a Highly Polarized Carbon-Carbon Double Bond from Reaction of Malononitrile, Carbon Disulfide (CS2), and Oxiranes
作者
Yavari, I; Ghazanfarpour-Darjani, M; Solgi, Y; Ahmadian, S
[摘要]:An efficient synthesis of functionalized 2-(1,3-oxathiolan-2-ylidene) malononitriles containing a push-pull C = C bond via a simple reaction between malononitrile, CS2, and oxiranes in the presence of Et3N is described (Scheme 1).