One-Pot Asymmetric Synthesis of gamma-Nitroaldehydes from Aldehydes and Nitroalkanes through a Catalytic Tandem Reaction Using an Amino Add Lithium Salt

[摘要]：One-pot asymmetric synthesis of gamma-nitroaldehydes from aldehydes and nitroalkanes was achieved by a catalytic tandem reaction using a primary amino add lithium salt, O-tert-butyldiphenylsily L-tyrosine lithium salt, as a catalyst. Various aril, alkenyl, and alkyl aldehydes were converted into gamma-nitroaldehydes via in situ generation of nitroalkenes.

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