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Effect of the Temperature on the Composition of Lignin Pyrolysis Products

  作者 Jiang, GZ; Nowakowski, DJ; Bridgwater, AV  
  选自 期刊  ENERGY & FUELS;  卷期  2010年24-8;  页码  4470-4475  
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[摘要]The temperature dependence of the pyrolysis products of two types of lignin (Alcell lignin and Asian lignin) was investigated using pyrolysis-gas chromatography-mass spectrometry (PyGC-MS). About 50 compounds were identified and quantified for each type of lignin over a temperature range of 400-800 degrees C. The maximum yield of phenolic compounds was obtained at 600 degrees C for both lignins, which was 17.2% for Alcell lignin and 15.5% for Asian lignin. Most of the phenolic compounds had an individual yield of less than 1%; however, for Alcell lignin, 5-hydroxyvanillin was the highest yield at 4.29 wt % on dry ash-free lignin, and for Asian lignin, 2-methoxy-4-vinylphenol was the highest yield at 4.15 wt A on dry ash-free lignin.

 
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