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Atomically Defined Rare-Earth Scandate Crystal Surfaces

  作者 Kleibeuker, JE; Koster, G; Siemons, W; Dubbink, D; Kuiper, B; Blok, JL; Yang, CH; Ravichandran, J; Ramesh, R; ten Elshof, JE; Blank, DHA; Rijnders, G  
  选自 期刊  ADVANCED FUNCTIONAL MATERIALS;  卷期  2010年20-20;  页码  3490-3496  
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[摘要]The fabrication of well-defined, atomically sharp substrate surfaces over a wide range of lattice parameters is reported, which is crucial for atomically regulated epitaxial growth of complex oxide heterostructures. By applying a framework for controlled selective wet etching of complex oxides on the stable rare-earth scandates (REScO3), a(pseudocubic) = 0.394-0.404 nm, the large chemical sensitivity of REScO3 to basic solutions is exploited, which results in reproducible, single-terminated surfaces. Time-of-flight mass-spectroscopy measurements show that after wet etching the surfaces are predominantly ScO2-terminated. Moreover, the morphology study of SrRuO3 thin-film growth gives no evidence for mixed termination. Therefore, it is concluded that the REScO3 surfaces are completely ScO2-terminated.

 
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