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Vicarious Nucleophilic Substitution of alpha-Hydrogen of BODIPY and Its Extension to Direct Ethenylation

  作者 LEEN VOLKER; VAN DER AUWERAER MARK; BOENS NOEL; DEHAEN WIM  
  选自 期刊  Organic Letters;  卷期  2011年13-6;  页码  1470-1473  
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[摘要]Direct, oxidizer-free substitution of the 3-hydrogen of BODIPY derivatives has been established through a vicarious nucleophilic substitution procedure. This methodology has been combined with a reversible Michael addition on nitrostyrenes to provide a novel, highly efficient entry to the valuable 3-styrylated BODIPY dyes.

 
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