Pd-Catalyzed Desulfitative Heck Coupline with Dioxygen as the Terminal Oxidant

[摘要]：A Pd-catalyzed desulfitative Heck-type reaction of aromatic sulfinic acid sodium salts with various olefins is developed with O-2 as the terminal oxidant under mild conditions. The presence of phosphane ligand DPEphos In anisole can significantly enhance the reaction selectivity.

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