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A Side-Chain Defunctionalization Approach Yields a Polymer Electrochrome Spray-Processable from Water

  作者 Beaujuge, PM; Amb, CM; Reynolds, JR  
  选自 期刊  ADVANCED MATERIALS;  卷期  2010年22-47;  页码  5383-5383  
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[摘要]A pi-conjugated electrochromic polymer (ECP) with alkyl ester side-chains is synthesized and subsequently defunctionalized to yield a polyionic salt readily soluble in water and further spray-processable from water. Upon neutralization, the defunctionalized polymer backbone recovers its electrochromic properties. The ability to print- or spray-process pi-conjugated ECPs from aqueous media offers a sustainable alternative to traditional organic solvent-processing methods and could impact the development of non-emissive flexible display technologies.

 
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