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Approaches to Solution-Processed Multilayer Organic Light-Emitting Diodes Based on Cross-Linking

  作者 Zuniga, CA; Barlow, S; Marder, SR  
  选自 期刊  CHEMISTRY OF MATERIALS;  卷期  2011年23-3;  页码  658-681  
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[摘要]The fabrication of multilayer organic light-emitting diodes through solution processing presents challenges, especially regarding dissolution of the first layer during deposition of a second layer. One possible approach to this problem is to insolubilize the first layer using cross-linking. Cross-linking has also been used to control the morphological stability and aggregation phenomena of the active organic materials. In this short review, we discuss the alternative chemically, thermally, and photo-chemically promoted cross-linking chemistries that have been examined in the context of organic light-emitting diodes including: the hydrolysis of silicon compounds to form siloxanes; the polymerization of styrene, acrylate, and oxetane groups; and the dimerization of trifluorovinyl ethers, benzocyclobutenes, and cinnamates.

 
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