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Towards an environmentally-friendly laboratory: dimensionality and reactivity in the mechanosynthesis of metal-organic compounds

  作者 STRUKIL VJEKOSLAV; FABIAN LASZLO; REID DAVID G; DUER MELINDA J; JACKSON GRAHAM J; ECKERTMAKSIC MIRJANA; FRISCIC TOMISLAV  
  选自 期刊  Chemical Communications;  卷期  2010年46-48;  页码  9191-9193  
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[摘要]We present a proof-of-principle study of an environmentally-friendly approach to laboratory research, in which the synthesis and structural characterisation of metal-organic complexes and frameworks are achieved without using bulk solvents; our study addresses the use of heteroditopic ligands for manipulating the dimensionality of metal-organic materials and describes how kinetic obstacles in such mechanosynthesis can be overcome.

 
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