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Unprecedented Elimination of Conjugated Phenylthioether Groups by Low-Valent Titanocene

  作者 RIBEIRO NIGEL; FETZER LUDIVINE; STREIFF STEPHANE; DESAUBRY LAURENT  
  选自 期刊  SYNLETT;  卷期  2010年-19;  页码  2928-2930  
  关联知识点  
 

[摘要]The first thioether elimination reaction utilizing a low-valent titanocene has been discovered. This reaction occurs under mild conditions and affords stereospecifically a variety of dienes and styrenes. Our data suggest that this new reaction involves an intermediate of dimerization of titanocene as the reactant responsible for this elimination.

 
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