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Syntheses of N-Alkylated Carbazolones via Pd(OAc)(2)-Mediated Intramolecular Coupling of N-Substituted 3-(Arylamino)cyclohex-2-enones

  作者 BI WENYING; YUN XILIU; FAN YANFENG; QI XIUXIANG; DU YUNFEI; HUANG JIANHUI  
  选自 期刊  SYNLETT;  卷期  2010年-19;  页码  2899-2904  
  关联知识点  
 

[摘要]A variety of functionalized N-alkylated carbazolones were prepared via N-alkylation of 3-(arylamino) cyclohex-2-enones followed by an intramolecular oxidative coupling mediated by Pd(OAc)(2) under an oxygen atmosphere. This approach adopts an inverted sequence, consisting of the conventional annulation and subsequent N-alkylation.

 
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