Cross-Coupling Reactions between C(sp(2))-H and C(sp(3))-H Bonds via Sequential Dehydrogenation and C-H Insertion

[摘要]：Formal C(sp(2))-H and C(sp(3))-H cross-coupling reactions were carried out by iridium-catalyzed transfer dehydrogenation of primary alcohols and sequential manganese-catalyzed insertion of the formed aldehydes into a carbon-hydrogen bond of aromatic or olefinic compounds.

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