Contrasting reactivity of anionic boron- and gallium-containing NHC analogues: E-C vs. E-M bond formation (E = B, Ga)

[摘要]：The anionic Group 13 NHC analogues [(CHNDipp)(2)E](-) (E = B or Ga) display contrasting reactivity towards the half-sandwich titanium imido complex Cp*TiCl(NtBu)py; while the gallium system undergoes salt metathesis yielding the first example of a titanium gallyl compound, the more nucleophilic boryl anion generates a dearomatized pyridyl fragment via attack at the ligand 2-position.

[全文传递流程]：

一般上传文献全文的时限在1个工作日内