Complete disassembly of carbon disulfide by a ditantalum complex

[摘要]：The side-on end-on dinitrogen complex [PhP(CH2SiMe2NPh)(2)Ta](mu-H)(2)(mu-eta(2):eta(1)-N-2) reacts with CS2 with complete cleavage of both C=S double bonds and the formation of [PhP(CH2SiMe2NPh)(2)Ta](mu-S)(2)(mu-CH2), which has two bridging sulfides and a bridging methylene unit. Further reaction with H-2 produces CH4 and the disulfide complex.

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