Experimental and Theoretical Investigation into the Gold-Catalyzed Reactivity of Cyclopropenylmethyl Acetates

[摘要]：Cyclopropenylmethyl acetates have been shown to undergo rapid and stereoselective gold catalyzed rearrangement to Z-acetoxydienes in high yield. OFT calculations have shown that while several reaction pathways can be envisaged only a single, ring-opening one operates.

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