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Diluted manganese on the bond-centered site in germanium

  作者 Decoster, S; Cottenier, S; Wahl, U; Correia, JG; Pereira, LMC; Lacasta, C; Da Silva, MR; Vantomme, A  
  选自 期刊  Applied Physics Letters;  卷期  2010年97-15;  页码  151914-151914  
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[摘要]The functional properties of Mn-doped Ge depend to large extent on the lattice location of the Mn impurities. Here, we present a lattice location study of implanted diluted Mn by means of electron emission channeling. Surprisingly, in addition to the expected substitutional lattice position, a large fraction of the Mn impurities occupies the bond-centered site. Corroborated by ab initio calculations, the bond-centered Mn is related to Mn-vacancy complexes. These unexpected results call for a reassessment of the theoretical studies on the electrical and magnetic behavior of Mn-doped Ge, hereby including the possible role of Mn-vacancy complexes. (c) 2010 American Institute of Physics. [doi:10.1063/1.3501123]

 
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